How are quantum energies spaced ?


lead and mercury

In quantum systems, we find that the distribution of energy is not continuous.  Rather, energy is distributed in discrete elements.  The plot depicts the spacing of these discrete energy elements for three different situations. The allowed values for the energy are plotted as lines with increasing values from bottom to top. The total number of allowed energies is the same in all three situations, but the type of spacing looks rather different for each.

On the far left, the energy level spacing corresponds to a completely random distribution. There are clusters of levels very close together, as well as areas where the levels are very far apart.  For this case, one just "rolls dice" to determine the energy levels.  This way, it is easy to see that the areas where the spacing appears clustered arise from the fact that some numbers are arbitrarily rolled more than once.

On the far right is the exact opposite situation.  Here, it is evident that the energy spacing is extremely regular.  Each of the levels is spaced evenly.  This type of spacing could result from a familiar situation such as an ideal harmonic oscillator.

The plot on the left and the plot on the right result from situations that can be observed in nature.  However, the middle plot is even more consistent with nature.  Note that the spacing here is not as random as the left, but also not as regular as the right.  This spacing distribution is commonly found in actual many-body quantum systems such as nuclei.

A more mathematical understanding of the above plots can be obtained by analyzing the equations that correspond to each one.  The far left yields spacing plot known as the Poisson spacing distribution.  When the spacing distribution is analyzed more thoroughly, by taking the actual spacing divided by the average spacing, the resulting graph is similar to the function exp(-x), where x is the level spacing. This reaches a maximum when x = 0, meaning that the energy levels have a predisposed tendency to cluster together.  This kind of spacing distribution is directly related to an element of weak interaction within the system.  It is also evidence that a regular system will yield the chaotic Poisson spacing distribution. 

When the spacings of the middle plot are analyzed in the same manner, the resulting graph follows a function called the Wigner spacing distribution. Unlike the left plot, this plot results from stronger interaction within the system.  Any element of interaction will cause the energy levels to have a tendency to repel each other like opposite charges.  The right plot is representative of an ideal repellent situation.  The middle plot, however, shows what happens when randomness and regularity fight against each other.  The randomness dictates the levels to be clustered.  But instinctively, the levels also want to repel each other.  The spacing distribution of the middle plot is thus a combination of two ideal cases:  completely random and completely regular.  Also, this distribution is evidence that a chaotic system will yield the regular Wigner spacing distribution.


This webpage was written by Catherine Kennedy as part of her work in the 2004 Research Experience for Undergraduate (REU) program at MSU.